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17Cl35.45
Reactive Nonmetalsgas at STPP-block

Chlorine

Group: 17Period: 3Standard Atomic Weight: 35.45 u

Why is Chlorine in this position?

Understanding the scientific rationale behind Chlorine's position in the periodic table:

Group Assignment
Group 17

Belongs to Group 17 (Halogens) because it possesses 7 valence electrons (3s² 3p⁵).

Period Assignment
Period 3

Belongs to Period 3 because its valence electrons fill the n=3 shell.

Orbital Block
P-block

Belongs to the p-block because its differentiating electron occupies a 3p orbital.

Chemical Category
Reactive Nonmetals

Classified as a reactive nonmetal due to its high electronegativity (3.16) and strong halogen chemical reactivity.

Atomic Structure & Bohr Shell Model

Shell Distribution: [2, 8, 7]

Bohr Atomic Shell Model(2, 8, 7)

Hover or tap any shell orbit ring to inspect electron counts and 2n² capacities.

17 Protons (p⁺)18 Neutrons (n⁰)
KShell K: Electron 1 of 2Shell K: Electron 2 of 2LShell L: Electron 1 of 8Shell L: Electron 2 of 8Shell L: Electron 3 of 8Shell L: Electron 4 of 8Shell L: Electron 5 of 8Shell L: Electron 6 of 8Shell L: Electron 7 of 8Shell L: Electron 8 of 8MShell M: Electron 1 of 7Shell M: Electron 2 of 7Shell M: Electron 3 of 7Shell M: Electron 4 of 7Shell M: Electron 5 of 7Shell M: Electron 6 of 7Shell M: Electron 7 of 7ClZ = 17

Educational Note: This Niels Bohr planetary model visually illustrates principal quantum energy shells ($n=1, 2, 3\dots$) and electron counts. In modern quantum mechanics (Schrödinger model), electrons do not orbit in fixed circular planetary tracks, but exist as 3D probability clouds (orbitals: $s, p, d, f$) governed by the Heisenberg uncertainty principle.

Electron Shell Filling Breakdown

Shell K (n=1):2 / 2 electrons (100%)
Shell L (n=2):8 / 8 electrons (100%)
Shell M (n=3):7 / 18 electrons (39%)
Aufbau Electron Configuration
1s² 2s² 2p⁶ 3s² 3p⁵

Neutral ground state configuration. Valence electrons: 7.

Atomic & Quantum Properties

Electronegativity (Pauling)3.16 Pauling
1st Ionization Energy1251.2 kJ/mol
Electron Affinity-349 kJ/mol
Atomic Radius (empirical)79 pm
Common Oxidation States-1, +1, +3, +5, +7
Crystal StructureOrthorhombic

Physical & Thermal Properties

Density at STP0.00321 g/cm³
Melting Point-101.5 °C (171.6 K)
Boiling Point-34.04 °C (239.11 K)
Magnetic OrderingDiamagnetic
Discovery Year1774
Discovered ByCarl Wilhelm Scheele

Real-World Uses, Occurrence & Compounds

Major Industrial & Everyday Uses
  • Municipal drinking water disinfection and swimming pool sanitization
  • Polyvinyl chloride (PVC) pipe, flooring, and window frame manufacturing
  • Industrial paper pulp bleaching and textile finishing
  • Synthesis of chloroform, carbon tetrachloride, and countless pesticides
Occurrence in Nature

Abundant as chloride ions (Cl⁻) in ocean brine (1.9% by mass) and rock salt deposits (halite / NaCl).

Etymology & Name Origin

From Greek 'chloros' meaning pale green or yellow-green

Important Chemical Compounds
NaCl (Table salt)
HCl (Hydrochloric acid)
NaClO (Sodium hypochlorite / Bleach)
PVC (Polyvinyl chloride)
KClO₃ (Potassium chlorate)
Interesting Chemical Facts
  • Chlorine has the highest electron affinity (-349 kJ/mol) of any element in the periodic table, surpassing even fluorine.
  • Chlorine gas was the first chemical weapon used in warfare during World War I at the Second Battle of Ypres in 1915.
  • Your stomach produces hydrochloric acid (HCl) at a pH of 1.5 to 2.0 to digest proteins and destroy pathogens.
Safety & Handling Note

Extremely toxic and suffocating gas that attacks moist lung tissues to form hydrochloric acid, causing pulmonary edema.