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91Pa231.04
Actinidessolid at STPF-block

Protactinium

Group: f-blockPeriod: 7Standard Atomic Weight: 231.04 u

Why is Protactinium in this position?

Understanding the scientific rationale behind Protactinium's position in the periodic table:

Group Assignment
Group Lanthanide / Actinide

Actinide series element filling the 5f subshell.

Period Assignment
Period 7

Belongs to Period 7 because its outermost electrons occupy n=7.

Orbital Block
F-block

Belongs to the f-block because its valence electrons populate 5f orbitals (5f² 6d¹ 7s²).

Chemical Category
Actinides

Classified as an actinide radioactive metal.

Atomic Structure & Bohr Shell Model

Shell Distribution: [2, 8, 18, 32, 20, 9, 2]

Bohr Atomic Shell Model(2, 8, 18, 32, 20, 9, 2)

Hover or tap any shell orbit ring to inspect electron counts and 2n² capacities.

91 Protons (p⁺)140 Neutrons (n⁰)
KShell K: Electron 1 of 2Shell K: Electron 2 of 2LShell L: Electron 1 of 8Shell L: Electron 2 of 8Shell L: Electron 3 of 8Shell L: Electron 4 of 8Shell L: Electron 5 of 8Shell L: Electron 6 of 8Shell L: Electron 7 of 8Shell L: Electron 8 of 8MShell M: Electron 1 of 18Shell M: Electron 2 of 18Shell M: Electron 3 of 18Shell M: Electron 4 of 18Shell M: Electron 5 of 18Shell M: Electron 6 of 18Shell M: Electron 7 of 18Shell M: Electron 8 of 18Shell M: Electron 9 of 18Shell M: Electron 10 of 18Shell M: Electron 11 of 18Shell M: Electron 12 of 18Shell M: Electron 13 of 18Shell M: Electron 14 of 18Shell M: Electron 15 of 18Shell M: Electron 16 of 18Shell M: Electron 17 of 18Shell M: Electron 18 of 18NShell N: Electron 1 of 32Shell N: Electron 2 of 32Shell N: Electron 3 of 32Shell N: Electron 4 of 32Shell N: Electron 5 of 32Shell N: Electron 6 of 32Shell N: Electron 7 of 32Shell N: Electron 8 of 32Shell N: Electron 9 of 32Shell N: Electron 10 of 32Shell N: Electron 11 of 32Shell N: Electron 12 of 32Shell N: Electron 13 of 32Shell N: Electron 14 of 32Shell N: Electron 15 of 32Shell N: Electron 16 of 32Shell N: Electron 17 of 32Shell N: Electron 18 of 32Shell N: Electron 19 of 32Shell N: Electron 20 of 32Shell N: Electron 21 of 32Shell N: Electron 22 of 32Shell N: Electron 23 of 32Shell N: Electron 24 of 32Shell N: Electron 25 of 32Shell N: Electron 26 of 32Shell N: Electron 27 of 32Shell N: Electron 28 of 32Shell N: Electron 29 of 32Shell N: Electron 30 of 32Shell N: Electron 31 of 32Shell N: Electron 32 of 32OShell O: Electron 1 of 20Shell O: Electron 2 of 20Shell O: Electron 3 of 20Shell O: Electron 4 of 20Shell O: Electron 5 of 20Shell O: Electron 6 of 20Shell O: Electron 7 of 20Shell O: Electron 8 of 20Shell O: Electron 9 of 20Shell O: Electron 10 of 20Shell O: Electron 11 of 20Shell O: Electron 12 of 20Shell O: Electron 13 of 20Shell O: Electron 14 of 20Shell O: Electron 15 of 20Shell O: Electron 16 of 20Shell O: Electron 17 of 20Shell O: Electron 18 of 20Shell O: Electron 19 of 20Shell O: Electron 20 of 20PShell P: Electron 1 of 9Shell P: Electron 2 of 9Shell P: Electron 3 of 9Shell P: Electron 4 of 9Shell P: Electron 5 of 9Shell P: Electron 6 of 9Shell P: Electron 7 of 9Shell P: Electron 8 of 9Shell P: Electron 9 of 9QShell Q: Electron 1 of 2Shell Q: Electron 2 of 2PaZ = 91

Educational Note: This Niels Bohr planetary model visually illustrates principal quantum energy shells ($n=1, 2, 3\dots$) and electron counts. In modern quantum mechanics (Schrödinger model), electrons do not orbit in fixed circular planetary tracks, but exist as 3D probability clouds (orbitals: $s, p, d, f$) governed by the Heisenberg uncertainty principle.

Electron Shell Filling Breakdown

Shell K (n=1):2 / 2 electrons (100%)
Shell L (n=2):8 / 8 electrons (100%)
Shell M (n=3):18 / 18 electrons (100%)
Shell N (n=4):32 / 32 electrons (100%)
Shell O (n=5):20 / 50 electrons (40%)
Shell P (n=6):9 / 72 electrons (13%)
Shell Q (n=7):2 / 98 electrons (2%)
Aufbau Electron Configuration
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 5f² 6s² 6p⁶ 6d¹ 7s²

Neutral ground state configuration. Valence electrons: 5.

Atomic & Quantum Properties

Electronegativity (Pauling)1.5 Pauling
1st Ionization Energy568 kJ/mol
Electron Affinity-53 kJ/mol
Atomic Radius (empirical)200 pm
Common Oxidation States+5, +4
Crystal StructureTetragonal

Physical & Thermal Properties

Density at STP15.37 g/cm³
Melting Point1568 °C (1841 K)
Boiling Point4027 °C (4300 K)
Magnetic OrderingParamagnetic
Discovery Year1913
Discovered ByKasimir Fajans & Oswald Helmuth Göhring; isolated by Otto Hahn & Lise Meitner (1917)

Real-World Uses, Occurrence & Compounds

Major Industrial & Everyday Uses
  • Nuclear physics fundamental radiochemistry research
  • Oceanographic deep-sea sediment radiometric dating (²³¹Pa / ²³⁰Th ratio)
  • Breeder reactor intermediate in the Thorium-232 to Uranium-233 cycle
Occurrence in Nature

Present in pitchblende uranium ore at roughly 3 parts per million.

Etymology & Name Origin

From Greek 'protos' meaning first or ancestor, because it decays into actinium

Important Chemical Compounds
Pa₂O₅ (Protactinium pentoxide)
PaCl₅ (Protactinium pentachloride)
Interesting Chemical Facts
  • In 1961, the UK Atomic Energy Authority spent $500,000 to process 60 tons of nuclear waste to isolate just 125 grams of 99.9% pure protactinium.
  • Protactinium becomes a superconductor at temperatures below 1.4 K.
  • The Protactinium-231 to Thorium-230 ratio in ocean floor sediments acts as an atomic clock for dating deep ocean current circulation over the last 100,000 years.
Safety & Handling Note

Extremely toxic and radiotoxic alpha emitter; accumulates in bones and kidneys.