#19 / 118
19K39.098
Alkali Metalssolid at STPS-block

Potassium

Group: 1Period: 4Standard Atomic Weight: 39.098 u

Why is Potassium in this position?

Understanding the scientific rationale behind Potassium's position in the periodic table:

Group Assignment
Group 1

Belongs to Group 1 because it has a single 4s¹ valence electron.

Period Assignment
Period 4

Belongs to Period 4 because its valence electron occupies the fourth energy shell (n=4).

Orbital Block
S-block

Belongs to the s-block because the differentiating electron enters the 4s subshell.

Chemical Category
Alkali Metals

Classified as an alkali metal due to its soft metallic consistency, low melting point, and electropositive cation formation (K⁺).

Atomic Structure & Bohr Shell Model

Shell Distribution: [2, 8, 8, 1]

Bohr Atomic Shell Model(2, 8, 8, 1)

Hover or tap any shell orbit ring to inspect electron counts and 2n² capacities.

19 Protons (p⁺)20 Neutrons (n⁰)
KShell K: Electron 1 of 2Shell K: Electron 2 of 2LShell L: Electron 1 of 8Shell L: Electron 2 of 8Shell L: Electron 3 of 8Shell L: Electron 4 of 8Shell L: Electron 5 of 8Shell L: Electron 6 of 8Shell L: Electron 7 of 8Shell L: Electron 8 of 8MShell M: Electron 1 of 8Shell M: Electron 2 of 8Shell M: Electron 3 of 8Shell M: Electron 4 of 8Shell M: Electron 5 of 8Shell M: Electron 6 of 8Shell M: Electron 7 of 8Shell M: Electron 8 of 8NShell N: Electron 1 of 1KZ = 19

Educational Note: This Niels Bohr planetary model visually illustrates principal quantum energy shells ($n=1, 2, 3\dots$) and electron counts. In modern quantum mechanics (Schrödinger model), electrons do not orbit in fixed circular planetary tracks, but exist as 3D probability clouds (orbitals: $s, p, d, f$) governed by the Heisenberg uncertainty principle.

Electron Shell Filling Breakdown

Shell K (n=1):2 / 2 electrons (100%)
Shell L (n=2):8 / 8 electrons (100%)
Shell M (n=3):8 / 18 electrons (44%)
Shell N (n=4):1 / 32 electrons (3%)
Aufbau Electron Configuration
1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹

Neutral ground state configuration. Valence electrons: 1.

Atomic & Quantum Properties

Electronegativity (Pauling)0.82 Pauling
1st Ionization Energy418.8 kJ/mol
Electron Affinity-48.4 kJ/mol
Atomic Radius (empirical)243 pm
Common Oxidation States+1
Crystal StructureBCC

Physical & Thermal Properties

Density at STP0.862 g/cm³
Melting Point63.5 °C (336.65 K)
Boiling Point759 °C (1032 K)
Magnetic OrderingParamagnetic
Discovery Year1807
Discovered ByHumphry Davy

Real-World Uses, Occurrence & Compounds

Major Industrial & Everyday Uses
  • Agricultural NPK fertilizers (potash / KCl)
  • Food preservation and electrolyte balance in human physiology
  • Manufacturing liquid soaps and soft detergents (KOH)
  • Specialty heat-transfer fluids in nuclear reactors (NaK alloy)
Occurrence in Nature

Abundant in ancient evaporated sea beds as sylvite (KCl), carnallite, and orthoclase feldspar rock.

Etymology & Name Origin

From English 'potash' (pot ashes); symbol K from Neo-Latin 'kalium'

Important Chemical Compounds
KCl (Potassium chloride)
KOH (Caustic potash)
KNO₃ (Saltpeter / Nitre)
KMnO₄ (Potassium permanganate)
Interesting Chemical Facts
  • Potassium burns with an unmistakable vivid lilac-violet flame.
  • The radioactive isotope Potassium-40 (⁴⁰K) naturally present in bananas makes humans slightly radioactive.
  • The human body requires ~3,500–4,700 mg of potassium daily to maintain healthy cardiac rhythm and nerve transmission.
Safety & Handling Note

Reacts violently and exothermically with water to liberate flammable hydrogen gas; store immersed in anhydrous mineral oil.