#69 / 118
69Tm168.93
Lanthanides (Rare Earths)solid at STPF-block

Thulium

Group: f-blockPeriod: 6Standard Atomic Weight: 168.93 u

Why is Thulium in this position?

Understanding the scientific rationale behind Thulium's position in the periodic table:

Group Assignment
Group Lanthanide / Actinide

Lanthanide series element filling the 4f subshell.

Period Assignment
Period 6

Belongs to Period 6 because its outermost electrons occupy n=6.

Orbital Block
F-block

Belongs to the f-block because valence electrons fill 4f orbitals (4f¹³ 6s²).

Chemical Category
Lanthanides (Rare Earths)

Classified as a lanthanide rare earth metal.

Atomic Structure & Bohr Shell Model

Shell Distribution: [2, 8, 18, 31, 8, 2]

Bohr Atomic Shell Model(2, 8, 18, 31, 8, 2)

Hover or tap any shell orbit ring to inspect electron counts and 2n² capacities.

69 Protons (p⁺)100 Neutrons (n⁰)
KShell K: Electron 1 of 2Shell K: Electron 2 of 2LShell L: Electron 1 of 8Shell L: Electron 2 of 8Shell L: Electron 3 of 8Shell L: Electron 4 of 8Shell L: Electron 5 of 8Shell L: Electron 6 of 8Shell L: Electron 7 of 8Shell L: Electron 8 of 8MShell M: Electron 1 of 18Shell M: Electron 2 of 18Shell M: Electron 3 of 18Shell M: Electron 4 of 18Shell M: Electron 5 of 18Shell M: Electron 6 of 18Shell M: Electron 7 of 18Shell M: Electron 8 of 18Shell M: Electron 9 of 18Shell M: Electron 10 of 18Shell M: Electron 11 of 18Shell M: Electron 12 of 18Shell M: Electron 13 of 18Shell M: Electron 14 of 18Shell M: Electron 15 of 18Shell M: Electron 16 of 18Shell M: Electron 17 of 18Shell M: Electron 18 of 18NShell N: Electron 1 of 31Shell N: Electron 2 of 31Shell N: Electron 3 of 31Shell N: Electron 4 of 31Shell N: Electron 5 of 31Shell N: Electron 6 of 31Shell N: Electron 7 of 31Shell N: Electron 8 of 31Shell N: Electron 9 of 31Shell N: Electron 10 of 31Shell N: Electron 11 of 31Shell N: Electron 12 of 31Shell N: Electron 13 of 31Shell N: Electron 14 of 31Shell N: Electron 15 of 31Shell N: Electron 16 of 31Shell N: Electron 17 of 31Shell N: Electron 18 of 31Shell N: Electron 19 of 31Shell N: Electron 20 of 31Shell N: Electron 21 of 31Shell N: Electron 22 of 31Shell N: Electron 23 of 31Shell N: Electron 24 of 31Shell N: Electron 25 of 31Shell N: Electron 26 of 31Shell N: Electron 27 of 31Shell N: Electron 28 of 31Shell N: Electron 29 of 31Shell N: Electron 30 of 31Shell N: Electron 31 of 31OShell O: Electron 1 of 8Shell O: Electron 2 of 8Shell O: Electron 3 of 8Shell O: Electron 4 of 8Shell O: Electron 5 of 8Shell O: Electron 6 of 8Shell O: Electron 7 of 8Shell O: Electron 8 of 8PShell P: Electron 1 of 2Shell P: Electron 2 of 2TmZ = 69

Educational Note: This Niels Bohr planetary model visually illustrates principal quantum energy shells ($n=1, 2, 3\dots$) and electron counts. In modern quantum mechanics (Schrödinger model), electrons do not orbit in fixed circular planetary tracks, but exist as 3D probability clouds (orbitals: $s, p, d, f$) governed by the Heisenberg uncertainty principle.

Electron Shell Filling Breakdown

Shell K (n=1):2 / 2 electrons (100%)
Shell L (n=2):8 / 8 electrons (100%)
Shell M (n=3):18 / 18 electrons (100%)
Shell N (n=4):31 / 32 electrons (97%)
Shell O (n=5):8 / 50 electrons (16%)
Shell P (n=6):2 / 72 electrons (3%)
Aufbau Electron Configuration
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹³ 5s² 5p⁶ 6s²

Neutral ground state configuration. Valence electrons: 15.

Atomic & Quantum Properties

Electronegativity (Pauling)1.25 Pauling
1st Ionization Energy596.7 kJ/mol
Electron Affinity-50 kJ/mol
Atomic Radius (empirical)175 pm
Common Oxidation States+3
Crystal StructureHCP

Physical & Thermal Properties

Density at STP9.32 g/cm³
Melting Point1545 °C (1818 K)
Boiling Point1950 °C (2223 K)
Magnetic OrderingParamagnetic
Discovery Year1879
Discovered ByPer Teodor Cleve

Real-World Uses, Occurrence & Compounds

Major Industrial & Everyday Uses
  • Portable medical and dental X-ray radiation sources (Thulium-170 requiring no electricity)
  • Thulium fiber lasers (2 μm wavelength) for prostate surgery and kidney stone ablation
  • Blue luminescent phosphors in euro banknote anti-counterfeiting security strips
  • High-efficiency metal halide lighting arc tubes
Occurrence in Nature

The least abundant stable lanthanide, extracted in trace amounts from monazite sand ores.

Etymology & Name Origin

From 'Thule', the ancient mythical Greek and Roman name for the northernmost realm (Scandinavia)

Important Chemical Compounds
Tm₂O₃ (Thulium oxide)
TmCl₃ (Thulium chloride)
Tm:YAG (Thulium laser crystal)
Interesting Chemical Facts
  • A pellet of Thulium-170 the size of a pencil eraser emits clean X-rays for an entire year, allowing portable medical X-ray machines in remote wilderness locations.
  • Per Teodor Cleve named thulium after 'Thule', the mystical land at the northern edge of the known ancient world.
  • Thulium is more expensive per gram than gold due to its rarity and the complex multi-stage separation required to isolate it.
Safety & Handling Note

Low biological toxicity; insoluble in water, behaves similarly to other heavy lanthanides.